An algebraic extension of Dirac quantization: Examples

An extension of the Dirac procedure for the quantization of constrained systems is necessary to address certain issues that are left open in Dirac's original proposal. These issues play an important role especially in the context of non-linear, diffeomorphism invariant theories such as general relativity. Recently, an extension of the required type was proposed by one of us using algebraic quantization methods. In this paper, the key conceptual and technical aspects of the algebraic program are illustrated through a number of finite dimensional examples. The choice of examples and some of the analysis is motivated by certain peculiar problems endemic to quantum gravity. However, prior knowledge of general relativity is not assumed in the main discussion. Indeed, the methods introduced and conclusions arrived at are applicable to any system with first class constraints. In particular, they resolve certain technical issues which are present also in the reduced phase space approach to quantization of these systems.Comment: 43 pages, Latex, CGPG-94/6-1. (References added; particularly to earlier work by C.J.Isham using group theoretic ideas, in the introduction.

An algebraic approach to the quantization of cosntrained systems: finite dimensional examples

From the point of view of canonical quantum gravity, it has become imperative to find a framework for quantization which provides a {\em general} prescription to find the physical inner product, and is flexible enough to accommodate non-canonical variables. In this dissertation I consider an algebraic formulation of the Dirac approach to the quantization of constrained systems, due to A. Ashtekar. The Dirac quantization program is augmented by a general principle to find the inner product on physical states. Essentially, the Hermiticity conditions on physical operators determine this inner product. I also clarify the role in quantum theory of possible algebraic identities between the elementary variables. I use this approach to quantize various finite dimensional systems. Some of these models test the new aspects of the algebraic framework. Others bear qualitative similarities to \gr, and may give some insight into the pitfalls lurking in \qg. In (spatially compact) general relativity, the Hamiltonian is constrained to vanish. I present various approaches one can take to obtain an interpretation of the quantum theory of such ``dynamically constrained'' systems. I apply some of these ideas to the Bianchi I cosmology, and analyze the issue of the initial singularity in quantum theory.Comment: 124 pages, LaTeX (run twice before printing), SU-GP-92/8-1. (Minor corruption (extra blank line at line 2994) hopefully fixed.

Minisuperspaces: Observables and Quantization

A canonical transformation is performed on the phase space of a number of homogeneous cosmologies to simplify the form of the scalar (or, Hamiltonian) constraint. Using the new canonical coordinates, it is then easy to obtain explicit expressions of Dirac observables, i.e.\ phase space functions which commute weakly with the constraint. This, in turn, enables us to carry out a general quantization program to completion. We are also able to address the issue of time through ``deparametrization'' and discuss physical questions such as the fate of initial singularities in the quantum theory. We find that they persist in the quantum theory {\it inspite of the fact that the evolution is implemented by a 1-parameter family of unitary transformations}. Finally, certain of these models admit conditional symmetries which are explicit already prior to the canonical transformation. These can be used to pass to quantum theory following an independent avenue. The two quantum theories --based, respectively, on Dirac observables in the new canonical variables and conditional symmetries in the original ADM variables-- are compared and shown to be equivalent.Comment: 34 page

An Algebraic Approach to the Quantization of Cosntrained Systems: Finite Dimensional Examples

We discuss the statistical mechanics of magnetic flux lines in a finite-thickness slab of type-II superconductor. The long wavelength properties of a flux-line liquid in a slab geometry are described by a hydrodynamic free energy that incorporates the boundary conditions on the flux lines at the sample\u27s surface as a surface contribution to the free energy. Bulk and surface weak disorder are modeled via Gaussian impurity potentials. This free energy is used to evaluate the two-dimensional structure factor of the flux-line tips at the sample surface. We find that surface interaction always dominates in determining the decay of translational correlations in the asymptotic long-wavelength limit. On the other hand, such large length scales have not been probed by the decoration experiments. Our results indicate that the translational correlations extracted from the analysis of the Bitter patterns are indeed representative of behavior of flux lines in the bulk

Time-of-arrival in quantum mechanics

We study the problem of computing the probability for the time-of-arrival of a quantum particle at a given spatial position. We consider a solution to this problem based on the spectral decomposition of the particle's (Heisenberg) state into the eigenstates of a suitable operator, which we denote as the ``time-of-arrival'' operator. We discuss the general properties of this operator. We construct the operator explicitly in the simple case of a free nonrelativistic particle, and compare the probabilities it yields with the ones estimated indirectly in terms of the flux of the Schr\"odinger current. We derive a well defined uncertainty relation between time-of-arrival and energy; this result shows that the well known arguments against the existence of such a relation can be circumvented. Finally, we define a ``time-representation'' of the quantum mechanics of a free particle, in which the time-of-arrival is diagonal. Our results suggest that, contrary to what is commonly assumed, quantum mechanics exhibits a hidden equivalence between independent (time) and dependent (position) variables, analogous to the one revealed by the parametrized formalism in classical mechanics.Comment: Latex/Revtex, 20 pages. 2 figs included using epsf. Submitted to Phys. Rev.

Extraordinary elevation of the glass transition temperature of thin polymer films grafted to silicon oxide substrates

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